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Kobayashi, Kiyoshi*; Yoshida, Akira*; Matsushita, Yoshitaka*; Nishimura, Chikashi*; Oyama, Yukiko*; Miyoshi, Shogo*; Izumi, Fujio*; Igawa, Naoki; Yamaguchi, Shu*
no journal, ,
Conduction properties of oxide ions and crystal structure refinement of La
(SiO
)
O
have been made by A.C.-impedance, electro-motive force of oxygen concentration cell, X-ray and neutron diffraction methods using the sample fabricated by the sol-gel method. The crystal structure of the sample can be refined by structural model with 
6
/
space group. Oxide ion conductivity is found to be predominant in wide oxygen partial pressure and temperature range based on the conductivity and electro-motive force measurements.
Shimoyama, Tomotaka*; Tojo, Takeo*; Kawaji, Hitoshi*; Atake, Toru*; Fukazawa, Hiroshi; Igawa, Naoki
no journal, ,
Proton conductor BaZr
Sc
O
was synthesized by a solid state reaction method. Neutron diffraction experiments were performed for dried and D
O dissolute samples at 10 K. The observed data were analyzed by Rietveld method and Maximum Entropy method. It has been clarified that the deuterium exits at 12
site. It is founded that the distance between oxide ion site and deuterium site is shorter than the normal distance of O-D.
Li short-lived radiotracerSugai, Hiroyuki; Sataka, Masao; Okayasu, Satoru; Ichikawa, Shinichi; Nishio, Katsuhisa; Mitsuoka, Shinichi; Nakanoya, Takamitsu; Osa, Akihiko; Sato, Tetsuya; Hashimoto, Takashi; et al.
no journal, ,
Non-destructive and on-line Li diffusion experiments in Li ionic conductors are conducted using the short-lived 
-emitting radiotracer of Li. The radiotracers produced as an energetic and pulsed ion beam from TRIAC (Tokai Radioactive Ion Accelerator Complex) are implanted into a structural defect mediated Li ionic conductor of NaTl-type intermetallic compounds 
-LiGa. The diffusion coefficients obtained for -LiGa with Li content of 43-54 at.% at room temperature are discussed in terms of the interaction between Li-ion and the structural defects in the specimen, compared with the case of -LiAl and -LiIn. The nonlinear Li-content dependency of Li diffusion coefficients for -LiGa suggests that the Li diffusion with Li-deficient region is obstructed by the defect complex composed of vacancies at the Li sites.